1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Product name
	:	MMCD Ultra Conc Laundry Detergent Rain Water High SLS 
	
Recommended use
	:	Laundry	
Restrictions on use	:	Use only as directed on label
	
Manufacturer, importer, supplier
	:	Caldrea
1 Webster Street
Brantford   ON   N3T 5R1  	

Telephone	:	+18778651508
	
Emergency telephone number	:	24 Hour Transport & Medical Emergency Phone (866) 231-5406
24 Hour International Emergency Phone (952) 852-4647
24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666

2. HAZARDS IDENTIFICATION
Classification of the substance or mixture

Globally Harmonized System (GHS) Classification
Hazard classification	Hazard category	Hazards identification	Acute toxicityCategory 4	Harmful if swallowed.Skin irritationCategory 2	Causes skin irritation.Skin irritationCategory 2	Causes skin irritation.Respiratory sensitisationCategory 1	May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Labelling

Hazard symbols
Exclamation mark
Health hazard

Signal word
Danger 

Hazard statements 
Harmful if swallowed.
Causes skin irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Precautionary statements
If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Read label before use.
Specific treatment (see supplemental first aid instructions on this label).
IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
If experiencing respiratory symptoms: Call a POISON CENTER/doctor.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/ attention.
IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
Rinse mouth.
Take off contaminated clothing and wash before reuse.
Dispose of contents/ container to an approved incineration plant.
Wear protective gloves.
In case of inadequate ventilation wear respiratory protection.
Avoid breathing spray.
Wash hands thoroughly after handling.
Do not eat, drink or smoke when using this product.

Other hazards:	None identified

3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous chemicals present at or above reportable levels as defined by Canadian Hazardous Products Regulation are listed in this table.

Chemical name	CAS-No.	Weight percent	
Sodium Lauryl Sulfate	68585-47-7	 13.00 - 30.00	
Ethyl alcohol	64-17-5	 3.00 - 5.00	
Glycerin	56-81-5	 1.50 - 3.00	
Subtilisins (proteolytic enzymes)	9014-01-1	 0.10 - 1.00	

The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.

For additional information on product ingredients, see www.caldrea.com.

4. FIRST AID MEASURES
Description of first aid measures

Eye contact	:	No special requirements 
	
Skin contact	:	Wash off with plenty of water. Take off contaminated clothing and wash before reuse. 
	
Inhalation	:	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER/doctor. 
	
Ingestion	:	IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. 

 Most important symptoms and effects, both acute and delayed
Eyes	:	No adverse effects expected when used as directed.
	
Skin effect	:	Causes skin irritation.
No adverse effects expected when used as directed.
	
Inhalation	:	May cause allergic respiratory reaction.
	
Ingestion	:	Harmful if swallowed.
May cause irritation to mouth, throat and stomach.
May cause abdominal discomfort.
No adverse effects expected when used as directed.

Indication of any immediate medical attention and special treatment needed

See Description of first aid measures unless otherwise stated.

5. FIREFIGHTING MEASURES
Suitable extinguishing media	:	Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.	

Specific hazards during firefighting	:	Container may melt and leak in heat of fire. 	

Further information	:	Fight fire with normal precautions from a reasonable distance. Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus. 	

6. ACCIDENTAL RELEASE MEASURES
Personal precautions	:	Wear personal protective equipment.
Wash thoroughly after handling.
	
Environmental precautions	:	Outside of normal use, avoid release to the environment.

Methods and materials for containment and cleaning up	:	Dike large spills.
Clean residue from spill site.

7. HANDLING AND STORAGE
Handling
Precautions for safe handling	:	Avoid contact with skin, eyes and clothing.
For personal protection see section 8.
Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Avoid breathing vapours, mist or gas.
In case of insufficient ventilation, wear suitable respiratory equipment.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
	
Advice on protection against fire and explosion	:	Normal measures for preventive fire protection.

Storage
Requirements for storage areas and containers	:	Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Components	CAS-No.	mg/m3
 	ppm 
	Non-standard units	Basis	
Ethyl alcohol	64-17-5	-
1,000 ppm
	-
	ACGIH STEL

Personal protective equipment
Respiratory protection
	:	Use only with adequate ventilation.
Substantial amounts of mist/vapors can be controlled with local exhaust ventilation or respiratory protection.	
Hand protection
	:	Wear suitable gloves.
	
Eye protection
 :	No special requirements.
	
Skin and body protection
:	No special requirements.
	
Hygiene measures	:	Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Smoking, eating and drinking should be prohibited in the application area. 

9. PHYSICAL AND CHEMICAL PROPERTIES

Form	:	liquid
	
Color	:	Light
	
Odour	:	floral
	
Odour Threshold	:	Test not applicable for this product type
	
pH 	:	8.0
	
Melting point/freezing point	:	Test not applicable for this product type
	
Initial boiling point and boiling range	:	Test not applicable for this product type
	
Flash point	:	does not flash

Evaporation rate	:	Test not applicable for this product type

Flammability (solid, gas) 	:	Does not sustain combustion.

Upper/lower flammability or explosive limits
	:	Test not applicable for this product type

Vapour pressure	:	Test not applicable for this product type

Vapour density	:	Test not applicable for this product type

Relative density	:	1.039 g/cm3 	

Solubility(ies)	:	completely soluble

Partition coefficient: n-octanol/water
	:	Test not applicable for this product type

Auto-ignition temperature 	:	Test not applicable for this product type

Decomposition temperature 	:	Test not applicable for this product type

Viscosity, dynamic	:	200 mPa.s
at 25 C

Viscosity, kinematic	:	Test not applicable for this product type

Oxidizing properties	:	Test not applicable for this product type	

Volatile Organic Compounds 
Total VOC (wt. %)*	:	5.9 %	- additional exemptions may apply
*as defined by US Federal and State Consumer Product Regulations	

Other information	:	None identified	:	Test not applicable for this product type

10. STABILITY AND REACTIVITY
Reactivity	:	No dangerous reaction known under conditions of normal use.

Chemical stability	:	Stable under recommended storage conditions.
	
Possibility of hazardous reactions	:	If accidental mixing occurs and toxic gas is formed, exit area immediately. Do not return until well ventilated.

Conditions to avoid	:	Direct sources of heat.

Incompatible materials	:	Do not mix with bleach or any other household cleaners.
Strong bases

Hazardous decomposition products	:	Thermal decomposition can lead to release of irritating gases and vapours.

11. TOXICOLOGICAL INFORMATION
Acute oral toxicity	:	LD50    1790 mg/kg	Acute inhalation toxicity	:	LC50   > 10 mg/L	
Acute dermal toxicity	:	LD50    > 5000 mg/kg
	
GHS Properties	Classification	Routes of entry	Acute toxicity	Category 4
	Oral
	Acute toxicity	No classification proposed
	Dermal
	Acute toxicity	No classification proposed
	Inhalation - Dust and Mist
	Acute toxicity	No classification proposed
	Inhalation - Vapour
	Acute toxicity	No classification proposed
	Inhalation - Gas
	Skin irritation	Category 2
	-
	Skin irritation	Category 2
	-
	Serious eye damage/eye irritation	No classification proposed
	-
	Eye irritation	No classification proposed
	-
	Skin sensitisation	No classification proposed
	-
	Skin sensitisation	No classification proposed
	-
	Respiratory sensitisation	Category 1
	-
	Respiratory sensitisation	No classification proposed
	-
	Germ cell mutagenicity	No classification proposed
	-
	Carcinogenicity	No classification proposed
	-
	Reproductive toxicity	No classification proposed
	-
	Specific target organ toxicity - single exposure	No classification proposed
	-
	Specific target organ toxicity - repeated exposure	No classification proposed
	-
	Aspiration hazard	No classification proposed
	-
	
Aggravated Medical Condition	:	None known.	

12. ECOLOGICAL INFORMATION
Product : The product itself has not been tested.

Toxicity
The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions.

Toxicity to fish
ComponentsEnd point	Species	Value	Exposure time	Sodium Lauryl Sulfate	flow-through test LC50  Read-across (Analogy)  
	Danio rerio (zebra fish)	1.3 mg/l

	96 h
	
flow-through test  NOEC   Read-across (Analogy)  
Pimephales promelas (fathead minnow)> 1.357 mg/l
42 d
Ethyl alcohol	 LC50    
	Fish	11,200 mg/l

	96 h

Glycerin	 LC50    
	Oncorhynchus mykiss (rainbow trout)	51,000 - 57,000 mg/l

	96 h

Subtilisins (proteolytic enzymes)	 LC50  Measured  OECD Test Guideline 203
	Oncorhynchus mykiss (rainbow trout)	8.2 mg/l

	96 h
	
flow-through test  NOEC     OECD Guideline 210 (Fish, Early-Life Stage Toxicity Test)
Pimephales promelas (fathead minnow)0.042 mg/l
32 d
Toxicity to aquatic invertebrates
ComponentsEnd point	Species	Value	Exposure time	Sodium Lauryl Sulfate	static test EC50 Read-across (Analogy) 
	Daphnia magna (Water flea)

2.8 mg/l

	48 h
	
	flow-through test NOEC  Measured
	Ceriodaphnia dubia	0.88 mg/l
	7 d	
Ethyl alcohol	static test LC50  
	Ceriodaphnia dubia

5,012 mg/l

	48 h
	
	 NOEC  
	Daphnia magna	9.6 mg/l
	9 d	
Glycerin	 LC50  
	Daphnia magna (Water flea)
	1,955 mg/l

	48 h

Subtilisins (proteolytic enzymes)	semi-static EC50 MeasuredOECD Test Guideline 202 
	Daphnia magna (Water flea)
	0.170 mg/l

	48 h
	
	flow-through test NOEC  Measured
OECD Guideline 211 (Daphnia magna Reproduction Test)	Daphnia magna	0.324 mg/l
	21 d	

Toxicity to aquatic plants
ComponentsEnd point	Species	Value	Exposure time	Sodium Lauryl Sulfate	static test EC10  
	Desmodesmus subspicatus (green algae)
	5.4 mg/l
	72 h
	
Ethyl alcohol	Static EC50  
	Chlorella vulgaris (Fresh water algae)
	275 mg/l
	72 h
	
Glycerin	 EC10  
	Microcystis aeruginosa (blue-green algae)
	2,900 mg/l
	168 h
	
Subtilisins (proteolytic enzymes)	 ErC50  Measured
OECD Test Guideline 201 NOEC  Measured
OECD Test Guideline 201	Pseudokirchneriella subcapitata (green algae)
Pseudokirchneriella subcapitata (green algae)
	0.83 mg/l
0.317 mg/l
	72 h
72 h

Persistence and degradability
Component	Biodegradation	Exposure time	Summary	
Sodium Lauryl Sulfate	100 %  		Readily biodegradable.
Ethyl alcohol	97 %  	28 d	Readily biodegradable.
Glycerin	94 %  	24 h	Readily biodegradable.
Subtilisins (proteolytic enzymes)	100 %  	29 d	Readily biodegradable.
Bioaccumulative potential 

Component	Bioconcentration factor (BCF)	Partition Coefficient n-Octanol/water (log)	
Sodium Lauryl Sulfate	No data available< 2.1 
Ethyl alcohol	3.2 estimated-0.35 Measured
Glycerin	0.89 estimated-1.76 
Subtilisins (proteolytic enzymes)	No data available-3.1 Measured

Mobility 

Component	End point	Value	
Sodium Lauryl Sulfate	log Koc 2.5 - 3.19 

Ethyl alcohol	No data available
Glycerin	No data available-
Subtilisins (proteolytic enzymes)	No data available

PBT and vPvB assessment 
Component	Results	
Sodium Lauryl Sulfate	Not fulfilling PBT and vPvB criteria
	
Ethyl alcohol	Not fulfilling PBT and vPvB criteria
	
Glycerin	Not fulfilling PBT and vPvB criteria
	
Subtilisins (proteolytic enzymes)	Not fulfilling PBT and vPvB criteria

Other adverse effects	:	None known.

13. DISPOSAL CONSIDERATIONS
Consumer may discard empty container in trash, or recycle where facilities exist.

14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.

Land transport
Not classified as dangerous in the meaning of transport regulations.

Sea transport
Not classified as dangerous in the meaning of transport regulations.

Air transport
Not classified as dangerous in the meaning of transport regulations.

15. REGULATORY INFORMATION
California Prop. 65	:	This product is not subject to the reporting requirements under California's Proposition 65.	

16. OTHER INFORMATION
	HMIS Ratings 
Health	1
	
Flammability	0	
Reactivity	0
	
NFPA Ratings 
Health	1
	
Fire	0
	
Reactivity	0
	
Special	-

This information is being provided in accordance with Canada's Workplace Hazard Material Information System.  The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use.

Further information

This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.

Prepared by	SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)