1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Product name
	:	MMCD MSEC Fall Leaves Bulk 
	
Recommended use
	:	Hard Surface Cleaner

Restrictions on use	:	Use only as directed on label	
Manufacturer, importer, supplier
	:	S.C. Johnson & Son, Inc.
1525 Howe Street
Racine   WI   53403-2236  	

Telephone	:	+18005585252	

Emergency telephone number	:	 24 Hour Medical Emergency Phone: (866)231-5406
24 Hour Transport Emergency Phone: (800)424-9300

2. HAZARDS IDENTIFICATION
 Classification of the substance or mixture

Globally Harmonized System (GHS) Classification
This product does not meet the criteria for classification in any hazard class according to regulation OSHA 29 CFR 1910.1200.

Labelling

Precautionary statements
Other hazards:	None identified

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name	CAS-No.	Weight percent	
TRADE NAME	54464-57-2	 0.10 - 1.00	
2 methyl 4 isothiazolin-3-one	2682-20-4	 0.0001 - 0.10	
The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.

For additional information on product ingredients, see www.caldrea.com.

4. FIRST AID MEASURES
Description of first aid measures

Eye contact	:	No special requirements 
	
Skin contact	:	No special requirements 
	
Inhalation	:	No special requirements. 
	
Ingestion	:	No special requirements 

Most important symptoms and effects, both acute and delayed
Eyes	:	No adverse effects expected when used as directed.
	
Skin effect	:	No adverse effects expected when used as directed.
	
Inhalation	:	No adverse effects expected when used as directed.
	
Ingestion	:	No adverse effects expected when used as directed.

Indication of any immediate medical attention and special treatment needed

See Description of first aid measures unless otherwise stated.

5. FIREFIGHTING MEASURES
Suitable extinguishing media	:	Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.	

Specific hazards during firefighting	:	Container may melt and leak in heat of fire. 	

Further information	:	Fight fire with normal precautions from a reasonable distance. Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus. 	

6. ACCIDENTAL RELEASE MEASURES
Personal precautions	:	Wash thoroughly after handling.
	
Environmental precautions	:	Outside of normal use, avoid release to the environment.

Methods and materials for containment and cleaning up	:	Dike large spills.
Clean residue from spill site.

7. HANDLING AND STORAGE
Handling
Precautions for safe handling	:	Avoid contact with skin, eyes and clothing.
For personal protection see section 8.
KEEP OUT OF REACH OF CHILDREN AND PETS.
	
Advice on protection against fire and explosion	:	Normal measures for preventive fire protection.

Storage
Requirements for storage areas and containers	:	Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients unless noted in the table above.

Personal protective equipment
Respiratory protection
	:	No special requirements.
	
Hand protection
	:	No special requirements.
	
Eye protection
:	No special requirements.
	
Skin and body protection
:	No special requirements.
	
Hygiene measures	:	Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 

9. PHYSICAL AND CHEMICAL PROPERTIES

Form	:	liquid
	
Color	:	Colorless
	
Odour	:	Fruity

Odour Threshold	:	Test not applicable for this product type

pH 	:	7 - 7.5

Melting point/freezing point	:	0 °C
	
Initial boiling point and boiling range	:	Test not applicable for this product type

Flash point	:	does not flash

Evaporation rate	:	Test not applicable for this product type

Flammability (solid, gas) 	:	Does not sustain combustion.

Upper/lower flammability or explosive limits
	:	Test not applicable for this product type

Vapour pressure	:	Test not applicable for this product type

Vapour density	:	Test not applicable for this product type

Relative density	:	1.01 g/cm3 at 25 °C	

Solubility(ies)	:	soluble

Partition coefficient: n-octanol/water
	:	Test not applicable for this product type

Auto-ignition temperature 	:	Test not applicable for this product type

Decomposition temperature 	:	Test not applicable for this product type

Viscosity, dynamic	:	similar to water

Viscosity, kinematic	:	Test not applicable for this product type

			
Oxidizing properties	:	Test not applicable for this product type	

Volatile Organic Compounds 
Total VOC (wt. %)*	:	0.2 %	- additional exemptions may apply
*as defined by US Federal and State Consumer Product Regulations	

Other information	:	None identified	:	Test not applicable for this product type

10. STABILITY AND REACTIVITY
Reactivity	:	No dangerous reaction known under conditions of normal use.

Chemical stability	:	Stable under recommended storage conditions.

Possibility of hazardous reactions	:	If accidental mixing occurs and toxic gas is formed, exit area immediately. Do not return until well ventilated.

Conditions to avoid	:	Direct sources of heat.

Incompatible materials	:	None known.
	
Incompatible materials	:	Do not mix with bleach or any other household cleaners.
Strong bases

Hazardous decomposition products	:	Thermal decomposition can lead to release of irritating gases and vapours.

11. TOXICOLOGICAL INFORMATION
Acute oral toxicity	:	LD50    > 5000 mg/kg
	Acute inhalation toxicity	:	LC50   > 10 mg/L	
Acute dermal toxicity	:	LD50    > 5000 mg/kg
	
GHS Properties	Classification	Routes of entry	Acute toxicity	No classification proposed
	Oral
	Acute toxicity	No classification proposed
	Dermal
	Acute toxicity	No classification proposed
	Inhalation - Dust and Mist
	Acute toxicity	No classification proposed
	Inhalation - Vapour
	Acute toxicity	No classification proposed
	Inhalation - Gas
	Skin corrosion/irritation	No classification proposed
	-
	Serious eye damage/eye irritation	No classification proposed
	-
	Skin sensitisation	No classification proposed
	-
	Respiratory sensitisation	No classification proposed
	-
	Germ cell mutagenicity	No classification proposed
	-
	Carcinogenicity	No classification proposed
	-
	Reproductive toxicity	No classification proposed
	-
	Specific target organ toxicity - single exposure	No classification proposed
	-
	Specific target organ toxicity - repeated exposure	No classification proposed
	-
	Aspiration hazard	No classification proposed
	-
	
Aggravated Medical Condition	:	None known.	

12. ECOLOGICAL INFORMATION
Product : The product itself has not been tested.

Toxicity
The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions.

Toxicity to fish
ComponentsEnd point	Species	Value	Exposure time	TRADE NAME	static test LC50    OECD Test Guideline 203
	Lepomis macrochirus (Bluegill sunfish)	1.3 mg/l

	96 h
	
flow-through test  NOEC     
Danio rerio (zebra fish)0.16 mg/l
30 d
2 methyl 4 isothiazolin-3-one	 LC50    
	Oncorhynchus mykiss (rainbow trout)	4.77 mg/l

	96 h
	
  NOEC     
Oncorhynchus mykiss (rainbow trout)2.38 mg/l
98 d

Toxicity to aquatic invertebrates
ComponentsEnd point	Species	Value	Exposure time	TRADE NAME	static test EC50 MeasuredOECD Test Guideline 202 
	Daphnia magna (Water flea)
	1.38 mg/l

	48 h
	
	flow-through test NOEC  
	Daphnia magna	0.028 mg/l
	21 d	
2 methyl 4 isothiazolin-3-one	 EC50  
	Daphnia magna (Water flea)
	0.998 mg/l

	48 h
	
	 NOEC  
	Daphnia magna	0.359 mg/l
	21 d	

Toxicity to aquatic plants
ComponentsEnd point	Species	Value	Exposure time	TRADE NAME	 NOEC  
OECD Test Guideline 201	Desmodesmus subspicatus (green algae)
	2.6 mg/l
	72 h
	
2 methyl 4 isothiazolin-3-one	 EC10  
	Pseudokirchneriella subcapitata (green algae)
	0.024 mg/l
	24 h

Persistence and degradability
Component	Biodegradation	Exposure time	Summary	
TRADE NAME	0 %  	28 d	Not readily biodegradable.
2 methyl 4 isothiazolin-3-one	48 %  	28 d	Not readily biodegradable.

Bioaccumulative potential 

Component	Bioconcentration factor (BCF)	Partition Coefficient n-Octanol/water (log)	
TRADE NAME	850 Measured5.18 - 6.86 
2 methyl 4 isothiazolin-3-one	3 estimated-0.32 

Mobility 

Component	End point	Value	
TRADE NAME	No data available
2 methyl 4 isothiazolin-3-one	Koc
0.03 - 246.7  

PBT and vPvB assessment 
Component	Results	
TRADE NAME	Not fulfilling PBT and vPvB criteria
	
2 methyl 4 isothiazolin-3-one	Not fulfilling PBT and vPvB criteria

Other adverse effects	:	None known.

13. DISPOSAL CONSIDERATIONS
Consumer may discard empty container in trash, or recycle where facilities exist.

14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.

Land transport
Not classified as dangerous in the meaning of transport regulations.

Sea transport
Not classified as dangerous in the meaning of transport regulations.

Air transport
Not classified as dangerous in the meaning of transport regulations.

15. REGULATORY INFORMATION

Notification status	:	All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
	
California Prop. 65	:	This product is not subject to the reporting requirements under California's Proposition 65.	

16. OTHER INFORMATION
	HMIS Ratings 
Health	0
	
Flammability	0	
Reactivity	0

NFPA Ratings 
Health	0
	
Fire	0
	
Reactivity	0
	
Special	-
	
This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use.

Further information

This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.

Prepared by	SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)